|
KMID : 0370219780220040215
|
|
Yakhak Hoeji
1978 Volume.22 No. 4 p.215 ~ p.218
|
|
|
Elimination Reaction of alpha-Diethaylaminoacetophenone in the Formation of Hydantoin Derivatives
|
|
권순경/Kwon SK
|
|
|
Abstract
|
|
|
|
It is known that hydantoin derivative can be synthesized according to the method of Bucherer-Bergs, which employs the interaction of the carbonyl compounds with potassium cyanide and ammonium carbonate in dilute alcohol solution. In a converting study of alpha-diethylaminoacetophenone with KCN and (NH4)2CO3 to hydantoin, the attempted 5-diethylaminomethyl-5-phenylhydantoin was not formed. In this reaction diethylaminomethyl group was unexpectedly eliminated and 5-phenylhydantoin was obtained, instead of the anticipated compound.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|